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  2. Ruthenium, bis(acetato-kO,kO')[(1R)-[1,1'-binaphthalene]-2,2'-diylbis[bis(3,5-dimethylphenyl)phosphine-kP]]-, (OC-6-22)- (9CI)

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Brc1cnc(nc1)C
Pyrimidine, 5-bromo-2-methyl-
CCCP1(=O)OP(=O)(CCC)OP(=O)(O1)CCC
1,3,5,2,4,6-Trioxatriphosphorinane, 2,4,6-tripropyl-, 2,4,6-trioxide
CC1(C)OB(OC1(C)C)B1OC(C(O1)(C)C)(C)C
2,2'-Bi-1,3,2-dioxaborolane, 4,4,4',4',5,5,5',5'-octamethyl-
O=C(C=Cc1ccccc1)C=Cc1ccccc1.O=C(C=Cc1ccccc1)C=Cc1ccccc1.O=C(C=Cc1ccccc1)C=Cc1ccccc1.[Pd].[Pd]
Tris(dibenzylideneacetone)dipalladium
C1CCC(CC1)P(C1CCCCC1)C1CCCCC1.Cc1cc(C)c(c(c1)C)N1CCN(C1=[Ru](=Cc1ccccc1)(Cl)Cl)c1c(C)cc(cc1C)C
Ruthenium,[1,3-bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene]dichloro(phenylmethylene)(tricyclohexylphosphine)-, (SP-5-41)-

Ruthenium, bis(acetato-kO,kO')[(1R)-[1,1'-binaphthalene]-2,2'-diylbis[bis(3,5-dimethylphenyl)phosphine-kP]]-, (OC-6-22)- (9CI)

Cc1cc(C)cc(c1)P1(c2cc(C)cc(c2)C)c2ccc3c(c2c2c(P([Ru+2]451([O-]C(=[O]5)C)[O-]C(=[O]4)C)(c1cc(C)cc(c1)C)c1cc(C)cc(c1)C)ccc1c2cccc1)cccc3 Request for Quotation
Chemical Name: Ruthenium, bis(acetato-kO,kO')[(1R)-[1,1'-binaphthalene]-2,2'-diylbis[bis(3,5-dimethylphenyl)phosphine-kP]]-, (OC-6-22)- (9CI)
CAS Number: 374067-50-2
Product Number: AG003CBV(AGN-PC-0RDUF9)
Synonyms:
MDL No:
Molecular Formula: C56H54O4P2Ru
Molecular Weight: 954.0431

Identification/Properties

Properties
MP:
>100℃
Storage:
Inert atmosphere;2-8℃;
Form:
Solid
Computed Properties
Molecular Weight:
956.078g/mol
Hydrogen Bond Donor Count:
2
Hydrogen Bond Acceptor Count:
4
Rotatable Bond Count:
7
Exact Mass:
956.27g/mol
Monoisotopic Mass:
956.27g/mol
Topological Polar Surface Area:
74.6A^2
Heavy Atom Count:
63
Formal Charge:
0
Complexity:
1080
Isotope Atom Count:
0
Defined Atom Stereocenter Count:
0
Undefined Atom Stereocenter Count:
0
Defined Bond Stereocenter Count:
0
Undefined Bond Stereocenter Count:
0
Covalently-Bonded Unit Count:
4
Compound Is Canonicalized:
Yes

Safety Information

NMR Spectrum

Other Analytical Data

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Chemical Structure


(R)-Ru(OAc)2(DM-BINAP) is a valuable catalyst widely used in chemical synthesis due to its remarkable efficiency and selectivity in various asymmetric transformations. This complex has shown exceptional performance in promoting asymmetric hydrogenation reactions, enabling the synthesis of chiral compounds with high enantiomeric excess. Additionally, (R)-Ru(OAc)2(DM-BINAP) has been utilized in other important processes such as asymmetric allylic substitutions and asymmetric cyclopropanations, showcasing its versatility in complex molecule synthesis. This catalyst plays a crucial role in the advancement of organic chemistry by facilitating the creation of enantiomerically pure molecules, which are vital in the pharmaceutical and agrochemical industries. Its ability to catalyze a wide range of reactions with high efficiency makes (R)-Ru(OAc)2(DM-BINAP) a valuable tool for chemists striving to access complex chiral compounds in a stereocontrolled manner.